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Don't use the chemical cleaners, which can be harmful for the tiles cleaning. You can go through the vinegar or the homemade cleaning for cleaning solution or acid is also the good option for cleaning. You can also take the expertise advice too for cleaning.
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Clean grout with a mixture of ammonia, baking soda and vinegar. Bleach (do NOT mix with ammonia and rinse well if previously applied) works well for mildewed grout. For a grout cleaner that is child and pet safe, try toothpaste!
 

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Depending on the type of tile you have, Home Depot sells a sulfamic acid in the flooring department. Dilute properly, and make sure you have some windows open, possibly wear a mask.. Let the acid dwell on the grout for roughly 15 mins, then agitate grout. Clean up with basic equipment would be mop/bucket and wet vac.
 

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Determine Source of Stain to Find Best Cleaning Solution

As a 35 stone and tile industry veteran, it is best to first determine the source of the stain to find the best cleaning solution. For instance, the above mentioned use of Sulfamic Acid is best used for cleaning relatively new grout residue, but NOT for greasy stains. The mild acids are useful from melting away cement and grout residue.

For grease and other organic stains, mild alkali cleaners are best. And I DO suggest using professional grade cleaning products specifically made for stone and tile like HMK R55 Intensive Cleaner.

These products can save you time and can also do a better job than home remedies. Some of the options mentioned can actually damage tile (particularly marble tile) like vinegar and baking soda.

Baking Soda is pH 9.0 and can harm polished marble. Vinegar (depending on dilution) can be as acidic as 3 on the pH scale and can etch marble, travertine, limestone and can also eat away at grout, particularly unsanded grouts that are cement based.
 

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Oxygen bleach, which is one of the newest and most effective cleaning solutions, is available at home improvement stores. Use a mop or rag to remove the solution, rinse the tiles with clean water, then repeat as needed until the grout is as clean as new. A bleach pen can be used as well, and is often the perfect size to fit between tiles.
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For some stains, simple household items like vinegar or baking soda can be effective cleaners. Use vinegar diluted with an equal amount of water, or make a paste of baking soda and a bit of water to clean the grout with. Spray or dab the cleaner onto a small length of grout and scrub with a stiff brush. Scrubbing in small circles rather than straight up and down will remove more debris from the grout. Rinse well with water and mop up and remaining moisture with a sponge or paper towels.
 
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